Search results for "Area fraction"

showing 3 items of 3 documents

SINGLE-PEAK RESOLUTION CRITERIA FOR OPTIMIZATION OF MOBILE PHASE COMPOSITION IN LIQUID CHROMATOGRAPHY

2001

Three criteria that evaluate the single peak resolution (peak purity) in chromatography, the free height fraction, free area fraction, and valley ratio, are examined. The main advantages of these criteria against other criteria based on peak pair separation, are that the measurements are not affected by the identity of neighboring peaks and are normalized, which make them very intuitive. The methodology is illustrated through the isocratic separation of mixtures of several sulphonamides (sulphacetamide, sulphadiazine, sulphadimethoxine, sulphaguanidine, sulphamerazine, sulphamethazine, sulphamethoxazole, sulphamethizole, sulphamonomethoxine, sulphanilamide, sulphapyridine, sulphaquinoxaline…

Area fractionChromatographyResolution (mass spectrometry)ChemistryClinical BiochemistryAnalytical chemistryPharmaceutical ScienceFraction (chemistry)BiochemistryHigh-performance liquid chromatographySulphaquinoxalineAnalytical ChemistryPhase compositionSulphaguanidineSpectral purityJournal of Liquid Chromatography & Related Technologies
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Study of the performance of a resolution criterion to characterise complex chromatograms with unknowns or without standards

2017

The search for best conditions in liquid chromatography is routinely carried out with information provided by chemical standards. However, sometimes there are samples with insufficient knowledge about their chemical composition. In other cases, identities of the components are known, but there are no standards available, and in other cases the identities of peaks in chromatograms taken under different conditions are ambiguous. Most resolution criteria used to measure separation performance cannot be applied to these samples. In this work, a global resolution function valid for all situations was developed based on automatic measurements of peak prominences (area fraction exceeding the line …

Area fractionMeasure (data warehouse)Resolution (mass spectrometry)010405 organic chemistrybusiness.industryChemistryGeneral Chemical Engineering010401 analytical chemistryGeneral EngineeringAnalytical chemistryPattern recognitionFunction (mathematics)01 natural sciences0104 chemical sciencesAnalytical ChemistryLine (geometry)Comparison studyMedicinal herbsArtificial intelligenceDirect evaluationbusinessAnalytical Methods
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Comparison of the planimetry and point-counting methods for the assessment of the size of the mandible cysts on orthopantomograms

2011

Sahin, Bunyamin/0000-0001-8538-8443 WOS: 000304343300015 PubMed: 22143725 Objective: The purpose of this study is to compare the computer-assisted planimetry and point-counting methods in evaluating the sizes of the mandibular cysts with respect to their agreement and the time required to analyze. Study Design: The surface areas of 46 mandibular cyst lesions on orthopantomograms were estimated using the point-counting and computer-assisted planimetry methods. Three observers evaluated the outlined areas twice, using the point-counting (PC) and computer-assisted planimetry (CAP) methods with an interval of two weeks. In the planimetry technique, digitalized images and ImageJ software were us…

Area fractionOrthopantomogramIntraclass correlationmandibleCohen's kappaConsistency (statistics)Radiography PanoramicHumansMandibular DiseasesDiagnosis Computer-AssistedplanimetryGeneral DentistryMathematicsOrthodonticscystCystsMandibleAnatomy:CIENCIAS MÉDICAS [UNESCO]Mandibular cystPoint countingOtorhinolaryngologypoint-countingUNESCO::CIENCIAS MÉDICASSurgeryResearch-ArticleOral Surgery
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